Chapter 21. Nuclear Chemistry
- Identify common particles and energies involved in nuclear reactions
- Write and balance nuclear equations
Changes of nuclei that result in changes in their atomic numbers, mass numbers, or energy states are nuclear reactions. To describe a nuclear reaction, we use an equation that identifies the nuclides involved in the reaction, their mass numbers and atomic numbers, and the other particles involved in the reaction.
Types of Particles in Nuclear Reactions
Many entities can be involved in nuclear reactions. The most common are protons, neutrons, alpha particles, beta particles, positrons, and gamma rays, as shown in Figure 1. Protons (, also represented by the symbol ) and neutrons () are the constituents of atomic nuclei, and have been described previously. Alpha particles (, also represented by the symbol ) are high-energy helium nuclei. Beta particles (, also represented by the symbol ) are high-energy electrons, and gamma rays are photons of very high-energy electromagnetic radiation. Positrons (, also represented by the symbol ) are positively charged electrons (“anti-electrons”). The subscripts and superscripts are necessary for balancing nuclear equations, but are usually optional in other circumstances. For example, an alpha particle is a helium nucleus (He) with a charge of +2 and a mass number of 4, so it is symbolized . This works because, in general, the ion charge is not important in the balancing of nuclear equations.
Note that positrons are exactly like electrons, except they have the opposite charge. They are the most common example of antimatter, particles with the same mass but the opposite state of another property (for example, charge) than ordinary matter. When antimatter encounters ordinary matter, both are annihilated and their mass is converted into energy in the form of gamma rays (γ)—and other much smaller subnuclear particles, which are beyond the scope of this chapter—according to the mass-energy equivalence equation E = mc2, seen in the preceding section. For example, when a positron and an electron collide, both are annihilated and two gamma ray photons are created:
As seen in the chapter discussing light and electromagnetic radiation, gamma rays compose short wavelength, high-energy electromagnetic radiation and are (much) more energetic than better-known X-rays that can behave as particles in the wave-particle duality sense. Gamma rays are produced when a nucleus undergoes a transition from a higher to a lower energy state, similar to how a photon is produced by an electronic transition from a higher to a lower energy level. Due to the much larger energy differences between nuclear energy shells, gamma rays emanating from a nucleus have energies that are typically millions of times larger than electromagnetic radiation emanating from electronic transitions.
Balancing Nuclear Reactions
A balanced chemical reaction equation reflects the fact that during a chemical reaction, bonds break and form, and atoms are rearranged, but the total numbers of atoms of each element are conserved and do not change. A balanced nuclear reaction equation indicates that there is a rearrangement during a nuclear reaction, but of subatomic particles rather than atoms. Nuclear reactions also follow conservation laws, and they are balanced in two ways:
- The sum of the mass numbers of the reactants equals the sum of the mass numbers of the products.
- The sum of the charges of the reactants equals the sum of the charges of the products.
If the atomic number and the mass number of all but one of the particles in a nuclear reaction are known, we can identify the particle by balancing the reaction. For instance, we could determine that is a product of the nuclear reaction of and if we knew that a proton, , was one of the two products. Example 1 shows how we can identify a nuclide by balancing the nuclear reaction.
Balancing Equations for Nuclear Reactions
The reaction of an α particle with magnesium-25 () produces a proton and a nuclide of another element. Identify the new nuclide produced.
The nuclear reaction can be written as:
where A is the mass number and Z is the atomic number of the new nuclide, X. Because the sum of the mass numbers of the reactants must equal the sum of the mass numbers of the products:
Similarly, the charges must balance, so:
Check the periodic table: The element with nuclear charge = +13 is aluminum. Thus, the product is .
Check Your Learning
The nuclide combines with an electron and produces a new nucleus and no other massive particles. What is the equation for this reaction?
Following are the equations of several nuclear reactions that have important roles in the history of nuclear chemistry:
- The first naturally occurring unstable element that was isolated, polonium, was discovered by the Polish scientist Marie Curie and her husband Pierre in 1898. It decays, emitting α particles:
- The first nuclide to be prepared by artificial means was an isotope of oxygen, 17O. It was made by Ernest Rutherford in 1919 by bombarding nitrogen atoms with α particles:
- James Chadwick discovered the neutron in 1932, as a previously unknown neutral particle produced along with 12C by the nuclear reaction between 9Be and 4He:
- The first element to be prepared that does not occur naturally on the earth, technetium, was created by bombardment of molybdenum by deuterons (heavy hydrogen, ), by Emilio Segre and Carlo Perrier in 1937:
- The first controlled nuclear chain reaction was carried out in a reactor at the University of Chicago in 1942. One of the many reactions involved was:
Key Concepts and Summary
Nuclei can undergo reactions that change their number of protons, number of neutrons, or energy state. Many different particles can be involved in nuclear reactions. The most common are protons, neutrons, positrons (which are positively charged electrons), alpha (α) particles (which are high-energy helium nuclei), beta (β) particles (which are high-energy electrons), and gamma (γ) rays (which compose high-energy electromagnetic radiation). As with chemical reactions, nuclear reactions are always balanced. When a nuclear reaction occurs, the total mass (number) and the total charge remain unchanged.
Chemistry End of Chapter Exercises
- Write a brief description or definition of each of the following:
(b) α particle
(c) β particle
(e) γ ray
(g) mass number
(h) atomic number
- Which of the various particles (α particles, β particles, and so on) that may be produced in a nuclear reaction are actually nuclei?
- Complete each of the following equations by adding the missing species:
- Complete each of the following equations:
- Write a balanced equation for each of the following nuclear reactions:
(a) the production of 17O from 14N by α particle bombardment
(b) the production of 14C from 14N by neutron bombardment
(c) the production of 233Th from 232Th by neutron bombardment
(d) the production of 239U from 238U by bombardment
- Technetium-99 is prepared from 98Mo. Molybdenum-98 combines with a neutron to give molybdenum-99, an unstable isotope that emits a β particle to yield an excited form of technetium-99, represented as 99Tc*. This excited nucleus relaxes to the ground state, represented as 99Tc, by emitting a γ ray. The ground state of 99Tc then emits a β particle. Write the equations for each of these nuclear reactions.
- The mass of the atom is 18.99840 amu.
(a) Calculate its binding energy per atom in millions of electron volts.
(b) Calculate its binding energy per nucleon.
- For the reaction , if 100.0 g of carbon reacts, what volume of nitrogen gas (N2) is produced at 273K and 1 atm?
- alpha particle
- ( or or ) high-energy helium nucleus; a helium atom that has lost two electrons and contains two protons and two neutrons
- particles with the same mass but opposite properties (such as charge) of ordinary particles
- beta particle
- ( or or ) high-energy electron
- gamma ray
- ( or ) short wavelength, high-energy electromagnetic radiation that exhibits wave-particle duality
- nuclear reaction
- change to a nucleus resulting in changes in the atomic number, mass number, or energy state
- positron ( or )
- antiparticle to the electron; it has identical properties to an electron, except for having the opposite (positive) charge
Answers to Chemistry End of Chapter Exercises
1. (a) A nucleon is any particle contained in the nucleus of the atom, so it can refer to protons and neutrons. (b) An α particle is one product of natural radioactivity and is the nucleus of a helium atom. (c) A β particle is a product of natural radioactivity and is a high-speed electron. (d) A positron is a particle with the same mass as an electron but with a positive charge. (e) Gamma rays compose electromagnetic radiation of high energy and short wavelength. (f) Nuclide is a term used when referring to a single type of nucleus. (g) The mass number is the sum of the number of protons and the number of neutrons in an element. (h) The atomic number is the number of protons in the nucleus of an element.
3. (a) (b) (c) (d)
5. (a) (b) (c) (d)
7. (a) 148.8 MeV per atom; (b) 7.808 MeV/nucleon