Chapter 15. Nuclear Chemistry
HalfLife
Learning Objectives
 Define halflife.
 Determine the amount of radioactive substance remaining after a given number of halflives.
Whether or not a given isotope is radioactive is a characteristic of that particular isotope. Some isotopes are stable indefinitely, while others are radioactive and decay through a characteristic form of emission. As time passes, less and less of the radioactive isotope will be present, and the level of radioactivity decreases. An interesting and useful aspect of radioactive decay is halflife, which is the amount of time it takes for onehalf of a radioactive isotope to decay. The halflife of a specific radioactive isotope is constant; it is unaffected by conditions and is independent of the initial amount of that isotope.
Consider the following example. Suppose we have 100.0 g of tritium (a radioactive isotope of hydrogen). It has a halflife of 12.3 y. After 12.3 y, half of the sample will have decayed from hydrogen3 to helium3 by emitting a beta particle, so that only 50.0 g of the original tritium remains. After another 12.3 y—making a total of 24.6 y—another half of the remaining tritium will have decayed, leaving 25.0 g of tritium. After another 12.3 y—now a total of 36.9 y—another half of the remaining tritium will have decayed, leaving 12.5 g. This sequence of events is illustrated in Figure 15.1 “Radioactive Decay”.
Figure 15.1 Radioactive Decay
During each successive halflife, half of the initial amount will radioactively decay.
We can determine the amount of a radioactive isotope remaining after a given number halflives by using the following expression:
where n is the number of halflives. This expression works even if the number of halflives is not a whole number.
Example 3
The halflife of fluorine20 is 11.0 s. If a sample initially contains 5.00 g of fluorine20, how much remains after 44.0 s?
Solution
If we compare the time that has passed to the isotope’s halflife, we note that 44.0 s is exactly 4 halflives, so using the previous expression, n = 4. Substituting and solving results in the following:
Less than onethird of a gram of fluorine20 remains.
Test Yourself
The halflife of titanium44 is 60.0 y. A sample of titanium contains 0.600 g of titanium44. How much remains after 240.0 y?
Answer
0.0375 g
Halflives of isotopes range from fractions of a microsecond to billions of years. Table 15.2 “HalfLives of Various Isotopes” lists the halflives of some isotopes.
Table 15.2 HalfLives of Various Isotopes
Isotope  HalfLife 

^{3}H  12.3 y 
^{14}C  5730 y 
^{40}K  1.26 × 10^{9} y 
^{51}Cr  27.70 d 
^{90}Sr  29.1 y 
^{131}I  8.04 d 
^{222}Rn  3.823 d 
^{235}U  7.04 × 10^{8} y 
^{238}U  4.47 × 10^{9} y 
^{241}Am  432.7 y 
^{248}Bk  23.7 h 
^{260}Sg  4 ms 
Chemistry Is Everywhere: Radioactive Elements in the Body
You may not think of yourself as radioactive, but you are. A small portion of certain elements in the human body are radioactive and constantly undergo decay. The following table summarizes radioactivity in the normal human body.
Radioactive Isotope  HalfLife (y)  Isotope Mass in the Body (g)  Activity in the Body (decays/s) 

^{40}K  1.26 × 10^{9}  0.0164  4,340 
^{14}C  5,730  1.6 × 10^{−8}  3,080 
^{87}Rb  4.9 × 10^{10}  0.19  600 
^{210}Pb  22.3  5.4 × 10^{−10}  15 
^{3}H  12.3  2 × 10^{−14}  7 
^{238}U  4.47 × 10^{9}  1 × 10^{−4}  5 
^{228}Ra  5.76  4.6 × 10^{−14}  5 
^{226}Ra  1,620  3.6 × 10^{−11}  3 
The average human body experiences about 8,000 radioactive decays/s.
Most of the radioactivity in the human body comes from potassium40 and carbon14. Potassium and carbon are two elements that we absolutely cannot live without, so unless we can remove all the radioactive isotopes of these elements, there is no way to escape at least some radioactivity. There is debate about which radioactive element is more problematic. There is more potassium40 in the body than carbon14, and it has a much longer halflife. Potassium40 also decays with about 10 times more energy than carbon14, making each decay potentially more problematic. However, carbon is the element that makes up the backbone of most living molecules, making carbon14 more likely to be present around important molecules, such as proteins and DNA molecules. Most experts agree that while it is foolhardy to expect absolutely no exposure to radioactivity, we can and should minimize exposure to excess radioactivity.
What if the elapsed time is not an exact number of halflives? We can still calculate the amount of material we have left, but the equation is more complicated. The equation is
where e is the base of natural logarithms (2.71828182…), t is the elapsed time, and t_{1/2} is the halflife of the radioactive isotope. The variables t and t_{1/2} should have the same units of time, and you may need to make sure you know how to evaluate naturallogarithm powers on your calculator (for many calculators, there is an “inverse logarithm” function that you can use; consult your instructor if you are not sure how to use your calculator). Although this is a more complicated formula, the length of time t need not be an exact multiple of halflives.
Example 4
The halflife of fluorine20 is 11.0 s. If a sample initially contains 5.00 g of fluorine20, how much remains after 60.0 s?
Solution
Although similar to Example 3, the amount of time is not an exact multiple of a halflife. Here we identify the initial amount as 5.00 g, t = 60.0 s, and t_{1/2} = 11.0 s. Substituting into the equation:
amount remaining = (5.00 g) × e^{−(0.693)(60.0 s)/11.0 s}
Evaluating the exponent (and noting that the s units cancel), we get
amount remaining = (5.00 g) × e^{−3.78}
Solving, the amount remaining is 0.114 g. (You may want to verify this answer to confirm that you are using your calculator properly.)
Test Yourself
The halflife of titanium44 is 60.0 y. A sample of titanium contains 0.600 g of titanium44. How much remains after 100.0 y?
Answer
0.189 g
Key Takeaways
 Natural radioactive processes are characterized by a halflife, the time it takes for half of the material to decay radioactively.
 The amount of material left over after a certain number of halflives can be easily calculated.
Exercises

Do all isotopes have a halflife? Explain your answer.

Which is more radioactive—an isotope with a long halflife or an isotope with a short halflife?

How long does it take for 1.00 g of palladium103 to decay to 0.125 g if its halflife is 17.0 d?

How long does it take for 2.00 g of niobium94 to decay to 0.0625 g if its halflife is 20,000 y?

It took 75 y for 10.0 g of a radioactive isotope to decay to 1.25 g. What is the halflife of this isotope?

It took 49.2 s for 3.000 g of a radioactive isotope to decay to 0.1875 g. What is the halflife of this isotope?

The halflive of americium241 is 432 y. If 0.0002 g of americium241 is present in a smoke detector at the date of manufacture, what mass of americium241 is present after 100.0 y? After 1,000.0 y?

If the halflife of tritium (hydrogen3) is 12.3 y, how much of a 0.00444 g sample of tritium is present after 5.0 y? After 250.0 y?

Explain why the amount left after 1,000.0 y in Exercise 7 is not onetenth of the amount present after 100.0 y, despite the fact that the amount of time elapsed is 10 times as long.

Explain why the amount left after 250.0 y in Exercise 8 is not onefiftieth of the amount present after 5.0 y, despite the fact that the amount of time elapsed is 50 times as long.

An artifact containing carbon14 contains 8.4 × 10^{−9} g of carbon14 in it. If the age of the artifact is 10,670 y, how much carbon14 did it have originally? The halflife of carbon14 is 5,730 y.

Carbon11 is a radioactive isotope used in positron emission tomography (PET) scans for medical diagnosis. Positron emission is another, though rare, type of radioactivity. The halflife of carbon11 is 20.3 min. If 4.23 × 10^{−6} g of carbon11 is left in the body after 4.00 h, what mass of carbon11 was present initially?
Answers
1.
Only radioactive isotopes have a halflife.
3.
51.0 d
5.
25 y
7.
0.000170 g; 0.0000402 g
9.
Radioactive decay is an exponential process, not a linear process.
11.
3.1 × 10^{−8} g