{"id":7914,"date":"2021-06-08T21:58:07","date_gmt":"2021-06-08T21:58:07","guid":{"rendered":"https:\/\/opentextbc.ca\/introductorychemistry\/chapter\/polymers\/"},"modified":"2021-10-13T18:48:39","modified_gmt":"2021-10-13T18:48:39","slug":"polymers","status":"publish","type":"chapter","link":"https:\/\/opentextbc.ca\/introductorychemistry\/chapter\/polymers\/","title":{"raw":"Polymers","rendered":"Polymers"},"content":{"raw":"[latexpage]\r\n
\r\n

Learning Objectives<\/p>\r\n\r\n<\/header>\r\n

\r\n
    \r\n \t
  1. Define the terms monomer<\/em> and polymer<\/em>.<\/li>\r\n \t
  2. Draw the structure of a polymer from its monomer.<\/li>\r\n<\/ol>\r\n<\/div>\r\n<\/div>\r\nAmong other applications, organic chemistry has had a huge impact on the development of modern materials called polymers. Many objects in daily life are composed of polymers; curiously, so are several important biological materials.\r\n\r\nConsider a molecule with a double bond, such as ethylene:\r\n

    [latex]\\chemfig{(-[:120]H)(-[:-120]H)=(-[:60]H)(-[:-60]H)}[\/latex]<\/p>\r\nThe pi electrons of the\u00a0double bond can be\u00a0used to form a new sigma bond to join to other ethylene molecules. The end result is a long, virtually endless molecule:\r\n

    [latex]\\chemfig{(-[:120]H)(-[:-120]H)=(-[:60]H)(-[:-60]H)}+\\left[\\chemfig{(-[:120]H)(-[:-120]H)=(-[:60]H)(-[:-60]H)}\\right]_n \\longrightarrow \\chemfig{\\vdots-[:-30](-[:-60]H)(-[:-120]H)-[:30](-[:60]H)(-[:120]H)-[:-30](-[:-60]H)(-[:-120]H)-[:30](-[:60]H)(-[:120]H)-[:-30]\\vdots}[\/latex]<\/p>\r\nThis long, almost nonstop molecule is called a polymer<\/strong> (from the Greek meaning \u201cmany parts\u201d). The original part \u2014 ethylene \u2014 is called the monomer<\/strong> (meaning \u201cone part\u201d). The process of making a polymer is called polymerization<\/strong>. A polymer is an example of a macromolecule<\/em>, the name given to a large molecule.\r\n\r\nSimple polymers are named after their monomers; the ethylene polymer is formally called poly(ethylene), although in common use, the names are used without parentheses: polyethylene. Because adding one monomer to another forms this polymer, polyethylene is an example of a type of polymer called addition polymers<\/em>. Table\u00a016.4 \"Some Monomers and Their Addition Polymers\" lists some monomers and their addition polymers.\r\n\r\n\r\n\r\n\r\n\r\n\r\n\r\n
    Table 16.4 Some Monomers and Their Addition Polymers[footnote]Courtesy of UC Davis ChemWiki\\CC-BY-NC-SA-3.0[\/footnote]<\/caption>\r\n
    Monomer<\/th>\r\nPolymer Name<\/th>\r\nTrade Name<\/th>\r\nUses<\/th>\r\n<\/tr>\r\n
    [latex]\\chemfig{F_2C=CF_2}[\/latex]<\/td>\r\npolytetrafluoroethylene<\/td>\r\nTeflon<\/td>\r\nNon-stick coating for cooking utensils, chemically resistant specialty plastic parts, Gore-Tex<\/td>\r\n<\/tr>\r\n
    [latex]\\chemfig{H_2C=CCl_2}[\/latex]<\/td>\r\npolyvinylidene dichloride<\/td>\r\nSaran<\/td>\r\nClinging food wrap<\/td>\r\n<\/tr>\r\n
    [latex]\\chemfig{H_2C=CH{(CN)}}[\/latex]<\/td>\r\npolyacrylonitrile<\/td>\r\nOrlon, Acrilan, Creslan<\/td>\r\nFibres for textiles, carpets, upholstery<\/td>\r\n<\/tr>\r\n
    [latex]\\chemfig{{H_2}C=CH{(OCOC{H_3})}}[\/latex]<\/td>\r\npolyvinyl acetate<\/td>\r\n<\/td>\r\nElmer's glue, Silly Putty demo<\/td>\r\n<\/tr>\r\n
    [latex]\\chemfig{{H_2}C=C{(CH_3)}COOCH_3}[\/latex]<\/td>\r\npolymethyl methacrylate<\/td>\r\nPlexiglass, Lucite<\/td>\r\nStiff, clear, plastic sheets, blocks, tubing, and other shapes<\/td>\r\n<\/tr>\r\n<\/tbody>\r\n<\/table>\r\n
    \r\n

    Example 16.13<\/p>\r\n\r\n<\/header>\r\n

    \r\n\r\nDraw the polymer that results from the polymerization of tetrafluoroethylene.\r\n

    [latex]\\chemfig{(-[:120]F)(-[:-120]F)=(-[:60]F)(-[:-60]F)}[\/latex]<\/p>\r\nSolution<\/em>\r\nIn the case of this monomer, the double bond opens up and joins to other monomers, just as with ethylene. The polymer has this structure:\r\n

    [latex]\\chemfig{-[@{left,.75}]C(-[:90]F)(-[:-90]F)-C(-[:90]F)(-[:-90]F)-C(-[:90]F)(-[:-90]F)-C(-[:90]F)(-[:-90]F)-[@{right,0.25}:0]}\\polymerdelim[delimiters={[]}, height = 17pt]{left}{right}[\/latex]<\/p>\r\nTest Yourself<\/em>\r\nDraw the polymer that results from the polymerization of vinyl chloride.\r\n

    [latex]\\chemfig{(-[:120]H)(-[:-120]H)=(-[:60]H)(-[:-60]Cl)}[\/latex]<\/p>\r\nAnswer<\/em>\r\n[latex]\\chemfig{-[@{left,.75}]C(-[:90]H)(-[:-90]H)-C(-[:90]H)(-[:-90]Cl)-C(-[:90]H)(-[:-90]H)-C(-[:90]H)(-[:-90]Cl)-[@{right,0.25}:0]}\\polymerdelim[delimiters={[]}, height = 17pt]{left}{right}[\/latex]\r\n\r\n<\/div>\r\n<\/div>\r\nAnother type of polymer is the condensation polymer<\/em>, which is a polymer made when two different monomers react together and release some other small molecule as a product. We have already seen an example of this in the formation of an amide bond:\r\n

    [latex]\\chemfig{N(-[:180]R)(-[:60]H)-[:-60]H}+\\chemfig{(=[:90]O)(-[:-150]HO)-[:-30]R'}\\longrightarrow\\chemfig{N(-[:-90]H)(-[:150]R)-[:30](=[:90]O)(-[:-30]R')}\\hspace{1em}+\\hspace{1em}\\ce{H2O}[\/latex]<\/p>\r\nHere, H2<\/sub>O is released when the ends of the molecules react to form a polymer.\r\n\r\nRelated to condensation polymers are the copolymers<\/em>, polymers made from more than one type of monomer. For example, ethylene and propylene can be combined into a polymer that is a mixture of the two monomers. A common form of synthetic rubber called styrene butadiene rubber(SBR)<\/em> is made from two monomers: styrene and butadiene:\r\n

    [latex]\\chemfig{-[@{left,.50}]-[@{west,.25}]C-C=C-C-[@{east,.25}]C(-[:-90]*6(=-=-=-))-C-[@{right,0.50}:0]}\r\n\\polymerdelim[delimiters={[]}, height = 17pt]{left}{right}\r\n\\polymerdelim[delimiters={()}, height = 10pt, indice={}]{west}{east}[\/latex]<\/p>\r\nThe physical and chemical properties of polymers vary widely, based on their monomers, structures, and additives. Among the other properties that can be modified based on these factors include solubility in H2<\/sub>O and other solvents, melting point, flammability, colour, hardness, transparency, film thickness, wetability, surface friction, moldability, and particle size \u2014 the list goes on.\r\n\r\nThe uses of polymers are almost too numerous to consider. Anything that you might describe as \u201cplastic\u201d is likely a polymer. Polymers are used to make everything from toothbrushes to computer cases to automobile parts. Many epoxy-based adhesives are condensation polymers that adhere strongly to other surfaces. Polyurethane paints and coatings are polymers, as are the polyester fabrics used to make clothing. Nylon, Dacron, and Mylar are polymers (in fact, both Dacron and Mylar are forms of polyethylene terephthalate [PET]). The product known as Saran Wrap was originally constructed from Saran, a name for poly(vinylidene chloride), which was relatively impervious to oxygen and could be used as a barrier to help keep food fresh. (It has since been replaced with polyethylene, which is not as impervious to atmospheric oxygen.) Poly(vinyl chloride) is the third-most produced polymer [after poly(ethylene) and poly(propylene)] and is used to make everything from plastic tubing to automobile engine parts, water pipes to toys, flooring to waterbeds and pools.\r\n\r\nAll the polymers we have considered so far are based on a backbone of (largely) carbon. There is another class of polymers based on a backbone of Si and O atoms; these polymers are called silicones<\/strong>. The Si atoms have organic groups attached to them, so these polymers are still organic. One example of a silicone is as follows:\r\n

    [latex]\\chemfig{-[@{left,.50}]Si(-[:-90]*6(=-=-=-))(-[:90]H)-O-Si(-[:-90]*6(=-=-=-))(-[:90]H)-O-Si(-[:-90]*6(=-=-=-))(-[:90]H)-O-[@{right,0.50}:0]}\r\n\\polymerdelim[delimiters={[]}, height = 17pt]{left}{right}[\/latex]<\/p>\r\nSilicones are used to make oils and lubricants. They are also used as sealants for glass objects (such as aquariums) and films for waterproofing objects. Solid silicones are heat resistant and rubbery and are used to make cookware and electrical insulation.\r\n\r\nSome very important biological materials are polymers. Of the three major food groups, polymers are represented in two: proteins and carbohydrates. Proteins are polymers of amino acids, which are monomers that have an amine functional group and a carboxylic acid functional group. These two groups react to make a condensation polymer, forming an amide bond:\r\n

    [latex]\\chemfig{N(-[:180]R)(-[:60]H)-[:-60]H}+\\chemfig{(=[:90]O)(-[:-150]HO)-[:-30]R'}\\longrightarrow\\chemfig{N(-[:-90]H)(-[:150]R)-[:30](=[:90]O)(-[:-30]R')}\\hspace{1em}+\\hspace{1em}\\ce{H2O}[\/latex]<\/p>\r\nProteins are formed when hundreds or even thousands of amino acids form amide bonds to make polymers. Proteins play a crucial role in living organisms.\r\n\r\nA carbohydrate<\/em> is a compound that has the general formula Cn<\/em><\/sub>(H2<\/sub>O)n<\/em><\/sub>. Many carbohydrates are relatively small molecules, such as glucose:\r\n

    [latex]\\chemfig{H-[:-90](-[:-150]HO)(<[:-60, 1.5](-[:165]HO)(-[:-90]H)<[:15, 1.5](-[:90]H)(-[:-45]OH)>[:-15, 1.5]-[:15]OH)-[:-15, 1.5](-[:150]-[:90]OH)(-[:-90, 1.5]H)-[:15, 1.5]O-[:-60, 1.5]-[:-90]H}[\/latex]<\/p>\r\n

    Linking hundreds of glucose molecules together makes a relatively common material known as starch<\/em>:<\/p>\r\n

    [latex]\\chemfig{H-[:-90, 0.5](-[:-150, 0.5]HO)(<[:-60, 1.5](-[:165, 0.5]HO)(-[:-90]H)<[:15, 1.5](-[:90]H)(-[:-45]OH)>[:-15, 1.5]-[:15]H)-[:-15, 1.5](-[:150]-[:90, 0.5]OH)(-[:-90, 1.5]H)-[:15, 1.5]O-[:-60, 1.5]-[:-75]O-[:-15, 0.5](-[:90, 0.5]H)(<[:-60, 1.5](-[:165]HO)(-[:-90]H)<[:15, 1.5](-[:90]H)(-[:-45]OH)>[:-15, 1.5]-[:15]H)-[:-15, 1.5](-[:150]-[:90, 0.5]OH)(-[:-90, 1.5]H)-[:15, 1.5]O-[:-60, 1.5]-[:-75]O-[:-15, 0.5](-[:90, 0.5]H)(<[:-60, 1.5](-[:165]HO)(-[:-90]H)<[:15, 1.5](-[:90]H)(-[:-45]OH)>[:-15, 1.5]-[:15]H)-[:-15, 1.5](-[:150]-[:90, 0.5]OH)(-[:-90, 1.5]H)-[:15, 1.5]O-[:-60, 1.5]-[:-90]OH}[\/latex]<\/p>\r\nStarch is an important source of energy in the human diet. Note how individual glucose units are joined together. They can also be joined together in another way, like this:\r\n

    [latex]\\chemfig{H-[:-90](-[:-150]@{left,0.5}-[:-150, 0.3])(<[:-60, 1.5](-[:165]HO)(-[:-90]H)<[:15, 1.5](-[:90]H)(-[:-45]OH)>[:-15, 1.5])-[:-15, 1.5](-[:150]-[:90]OH)(-[:-90, 1.5]H)-[:15, 1.5]O-[:-60, 1.5]-[:30]O-[:-30](<[:30](-[:-100]-[:-75]OH)>[:-15, 1.2]O>[:45, 1.4])-[:60, 1.2](-[:180]HO)-[:-15](-[:60]OH)-[:15, 1.5]-[:-30]O-[@{right,0.5}:30]}\r\n\\polymerdelim[delimiters={[]}, height=50 pt]{left}{right}[\/latex]<\/p>\r\nThis polymer is known as cellulose<\/em>. Cellulose is a major component in the cell walls of plants. Curiously, despite the similarity in the building blocks, some animals (such as humans) cannot digest cellulose; those animals that can digest cellulose typically rely on symbiotic bacteria in the digestive tract for the actual digestion. Animals do not have the proper enzymes to break apart the glucose units in cellulose, so it passes through the digestive tract and is considered dietary fibre<\/em>.\r\n\r\nDeoxyribonucleic acid<\/em> (DNA<\/em>) and ribonucleic acid<\/em> (RNA<\/em>) are also polymers, composed of long, three-part chains consisting of phosphate groups, sugars with five\u00a0C atoms (ribose or deoxyribose), and N-containing rings referred to as bases<\/em>. Each combination of the three parts is called a nucleotide; DNA and RNA are essentially polymers of nucleotides that have rather complicated but intriguing structures (Figure 16.5 \"Nucleotides\"). DNA is the fundamental material in chromosomes and is directly responsible for heredity, while RNA is an essential substance in protein synthesis.\r\n\r\n[caption id=\"attachment_3276\" align=\"aligncenter\" width=\"310\"]\"Towering Figure 16.5 \"Nucleotides.\" The DNA in our cells is a polymer of nucleotides, each of which is composed of a phosphate group, a sugar, and a N-containing base.[\/caption]\r\n\r\n

    \r\n

    Key Takeaways<\/p>\r\n\r\n<\/header>\r\n

    \r\n